Congratulations on your new additions! And welcome to the forums.
I can't really say, here are some thoughts.
Is the male intact or neutered? If he's still intact, he could possibly get a little wilder. I've never had an intact male, so can't say for sure. Possibly also could be he knows there's a female around and has gotten a bit feisty due to frustration if he's intact.
It's not that unusual for this to happen though. There could be any number of reasons he decided to bite. Most of the time it's scent related, or something they don't like. Maybe he was a bit off due to being placed in the bonding pouch, don't really know for sure.
All I can say is continue with him as you have been, be patient and keep spending time with him, consistently. He's still pretty new to you and may just need more time.